The paper underlines the new role the National Libraries worldwide can play as electronic guides inside an organizational schedule where the meanings of collaboration and interactivity dominate. In the new electronic époque, where the need for an effective national and international policy in the field of librarianship, as expressed as a general cultural policy, is more than imperative, National Libraries with the Academic Libraries can lay out a match of innovative guidelines. The point is how to provide not only information but also real knowledge to the patrons and the librarians themselves and how the whole thing can be done under the prearrangements of accuracy, promptness and validity. In the electronic époque in which we live and work, we need the best results in the quickest time. We search for collaborative solutions worldwide; let's see how the National Libraries and Academic Libraries can be real e-educators.